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In solid-state physics, the work function (sometimes spelled workfunction) is the minimum thermodynamic work (i.e. energy) needed to remove an electron from a solid to a point in the vacuum immediately outside the solid surface. Here "immediately" means that the final electron position is far from the surface on the atomic scale, but still too close to the solid to be influenced by ambient electric fields in the vacuum. The work function is not a characteristic of a bulk material, but rather a property of the surface of the material (depending on crystal face and contamination). == Definition == The work function for a given surface is defined by the difference : where is the charge of an electron, is the electrostatic potential in the vacuum nearby the surface, and is the Fermi level (electrochemical potential of electrons) inside the material. The term is the energy of an electron at rest in the vacuum nearby the surface, and the meaning of the term is the thermodynamic work required to remove an electron from the material to a state of zero total energy. In words, the work function is thus defined as the thermodynamic work required to remove an electron from the material to a state at rest in the vacuum nearby the surface. In practice, one directly controls by the voltage applied to the material through electrodes, and the work function is generally a fixed characteristic of the surface material. Consequently, this means that when a voltage is applied to a material, the electrostatic potential produced in the vacuum will be somewhat lower than the applied voltage, the difference depending on the work function of the material surface. Rearranging the above equation, one has : where is the voltage of the material (as measured by a voltmeter, through an attached electrode), relative to an electrical ground that is defined as having zero Fermi level. The fact that depends on material surface means that the space between two dissimilar conductors will have a built-in electric field, even when those conductors are in total equilibrium with each other (electrically shorted to each other, and with equal temperatures). An example of this situation is depicted in the adjacent figure. As described in the next section, these built-in vacuum electric fields can have important consequences in some cases. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「work function」の詳細全文を読む スポンサード リンク
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